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Methodology advance at HZB: ionic liquids simplify laser experiments on liquid samples

An HZB team has developed a new approach to conduct photoemission spectroscopy of molecules in solution. This has been difficult up to now because the sample needed to be situated in vacuum – but liquids evaporate. The work has now demonstrated it is feasible to replace the solvent with an ionic liquid of low vapor pressure, which does not perturb the sample characteristics.  This allows the molecules to be excited with a laser pulse and to record the behaviour of the excited energy states. It provides insight into the physical and chemical processes of novel liquid energy materials that might be employed in organic solar cells or catalysts, for instance.